I believe one thing you want to do is switch the "Color Representation" over to Adobe RGB. I saw some insanely complicated (to my feeble brain) seminar on digital color, and the one thing I got out of it is that you should never use sRGB when taking the pics. I think it compresses the color palette or something along those lines.
edit - wow, I was actually right! See here... http://www.cambridgeincolour.com/tut...obeRGB1998.htm
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