yes, you should be able to find some stuff in pucon, but try to arrange something (especially a boat!!) beforehand.
lots of mellow rivers on the way between santiago and down there but it will be hard/impossible to rent equipment.
for the futa, I don't see you having a lot of fun on most of the stretches and especially in the big rapids as a class 3 paddler, but apparently some of the side creeks are easier. also better to arrange something beforehand.
maybe this will also be an option for you:
http://www.universalkayak.com/kayak_creek_fenix.html
universal kayaks really started off now, word of mouth by basti striebel was that their material is really very well matured now..
~#at night the highway's diesel roar/speaks to me and tells me more/than any book I've ever read/or anything you've ever said#~
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